Materials & Substrates

CTE (Metal)

/see-tee-ee,  met-l/
Measured in parts per million per degree Celsius (ppm/°C), the coefficient of thermal expansion of a metal describes the fractional change in its linear dimension as temperature rises or falls. For RF hardware this single number quietly dictates whether a hermetic seal survives, whether a die cracks, and whether a waveguide holds its electrical length. Common housing metals range from Invar near 1.2 ppm/°C to aluminum at 23.6 ppm/°C, an almost 20:1 spread. Because mismatched metals expand at different rates, a CTE mismatch between a carrier, a substrate, and a solder joint generates shear stress over every temperature cycle. Matching CTE across the stack is therefore a core discipline in microwave package, carrier, and thermal management design.
Unit: ppm/°C (10-6/K)
Cu / Al: 16.5 / 23.6 ppm/°C
Kovar / Invar: 5.5 / 1.2 ppm/°C

Why Metal CTE Drives RF Package Reliability

Every metal expands when heated because thermal energy increases the average spacing between atoms in its lattice. The coefficient of thermal expansion is simply the rate of that growth normalized to length and temperature. In a microwave assembly the consequences are mechanical rather than electrical at first glance: a copper carrier expands roughly three times faster than the GaAs or GaN die soldered on top of it, so as the part heats from a 175 °C reflow down to a 25 °C bench, the two materials try to shrink by different amounts and the solder bond absorbs the difference as shear strain. Over hundreds or thousands of thermal cycles that strain fatigues the joint, and in the worst case it fractures the semiconductor itself.

This is why package engineers do not pick metals for cost or machinability alone. A glass-to-metal feedthrough must use a sealing alloy whose CTE tracks the borosilicate glass across the full sealing temperature range, which is precisely why Kovar (an iron-nickel-cobalt alloy near 5.5 ppm/°C) became the standard hermetic lead material. Where dimensional stability dominates, Invar and its low-expansion cousins hold geometry to a few ppm. Where heat removal dominates, designers reach for high-conductivity copper or composites such as CuMo and CuW that trade some conductivity for a CTE tuned to silicon, GaAs, or alumina.

CTE is also mildly temperature dependent. Most handbook values are quoted as a mean over 20 to 100 °C, but the instantaneous coefficient rises with temperature for ordinary metals and behaves anomalously for Invar near its Curie point. For wide-temperature military and space hardware (often -55 to +125 °C), engineers integrate the curve rather than assuming a constant slope.

Governing Relationships

Linear thermal expansion:
ΔL = αL × L0 × ΔT

Volumetric expansion (isotropic):
αV ≈ 3 × αL

Differential (mismatch) strain:
ε = (α1 − α2) × ΔT = Δα × ΔT

Constrained peak stress in stiffer member:
σ ≈ E × Δα × ΔT

Where αL = linear CTE (ppm/°C), L0 = original length, ΔT = temperature change from the stress-free state, E = elastic modulus. Example: Cu (16.5) on GaAs (5.7) over ΔT = 150 °C gives ε ≈ 10.8 × 10-6 × 150 ≈ 1620 µε.

CTE of Common RF Metals and Alloys

Metal / AlloyCTE (ppm/°C, 20-100 °C)Thermal Cond. (W/m·K)Typical RF Use
Invar (Fe-36Ni)1.2~13Dimension-critical waveguide, reflectors
Tungsten (W)4.5~170Heat spreaders, CuW base metal
Molybdenum (Mo)4.8~138CuMo carriers, flanges
Kovar (Fe-Ni-Co)5.5~17Glass-to-metal hermetic seals, leads
CuW (85/15)~6.5~190GaAs / GaN die carriers
CuMo (15/85)~7.0~160Si / GaAs carriers, balanced CTE
Gold (Au)14.2~317Bonding, plating, AuSn solder
Copper (OFC)16.5~390Carriers, heat sinks, cavity walls
Brass (C260)~19~120Connectors, machined fittings
Aluminum 606123.6~167Housings, chassis, heat sinks
Common Questions

Frequently Asked Questions

What are the CTE values of common RF package metals?

Near room temperature: OFC copper ≈ 16.5 ppm/°C, aluminum 6061 ≈ 23.6, brass ≈ 19, gold ≈ 14.2, molybdenum ≈ 4.8, tungsten ≈ 4.5, Kovar ≈ 5.5 (30 to 200 °C), and Invar ≈ 1.2 up to its inflection near 230 °C. CuMo and CuW composites are tailored between 6 and 11 ppm/°C by metal ratio, which is why Kovar pairs with borosilicate sealing glass while aluminum housings need compliant solders or strain relief.

How do I calculate thermal stress from a CTE mismatch in a soldered RF assembly?

Differential strain is ε = Δα × ΔT, measured from the solder solidus down to operating temperature. For a fully constrained joint the peak stress in the stiffer member approaches σ ≈ E × Δα × ΔT. A GaAs MMIC (5.7) on a copper carrier (16.5) over a 150 °C swing yields about 1620 µε, enough to fatigue solder or crack die. Designers mitigate with CuMo or CuW carriers, AuSn versus SnPb solder choice, and thicker compliant bond lines.

Why is Invar used for dimensionally stable waveguide and antenna structures?

Invar (Fe-36Ni) holds a CTE near 1.2 ppm/°C because magnetostriction nearly cancels normal lattice expansion below its Curie point. A 1 m Invar run drifts only about 60 µm over a 50 °C swing versus roughly 1180 µm for aluminum, keeping electrical path length and cavity resonant frequency in tolerance. The trade-offs are higher density, low thermal conductivity near 13 W/m·K, magnetic behavior, and a CTE that climbs above the Curie temperature.

Materials Engineering

Build on a CTE-Matched Foundation

From Kovar hermetic packages to CuMo and CuW carriers for GaN and GaAs, our integrated assemblies are engineered for dimensional stability across the full mil-temp range. Talk to our materials team about your stack.

Get in Touch